Vast-temperature-window hydrogel electrolyte developed for aqueous zinc-ion battery


The 3D framework by the copolymerization of AM and MBA. Credit score: Kong Fantai

Researchers led by Prof. Hu Linhua from the Hefei Institutes of Bodily Science of the Chinese language Academy of Sciences and Prof. Ji Denghui from Shijiazhuang College have not too long ago developed a hydrogel electrolyte that endows batteries with higher stability in wider temperature vary (-20 levels Celsius to 60 levels Celsius), extra versatile system software, and bigger capability.

in article 1

The associated analysis was revealed in Chemical Engineering Journal.

Aqueous zinc-ion batteries are thought-about as potential options for standard lithium-ion batteries on account of their ample sources and improved security. The hydrogel electrolyte utilized in zinc-ion batteries helps enhance their security towards hearth and leakage in contrast with standard lithium-ion batteries. However there are nonetheless some issues resembling poor stability and efficiency below excessive circumstances.

The temperature window is a key drawback of electrolytes in batteries. To deal with this drawback, the joint crew developed a hydrogel electrolyte by in situ copolymerization of acrylamide (AM) and N,N ‘-methylene bisacrylamide (MBA) within the combination of water, glycerin, acetonitrile, and zinc sulfate. The copolymer of acrylamide and N,N ‘-methylene diacrylamide is the 3D framework of hydrogel electrolyte, and zinc salt is the zinc supply.

The copolymer elevated the proportion of intermolecular hydrogen bond between copolymer and water molecule, however decreased the proportion of intramolecular hydrogen bond between water molecule. The bonding interplay regulation can scale back the prospect of freezing at low temperature and evaporation at excessive temperature, which is helpful to develop the working temperature vary.

The steadiness of hydrogel electrolyte and battery system. Credit score: Kong Fantai

One other benefit of this hydrogel electrolyte is its good mechanical properties for versatile system purposes. On this research, the scientists discovered that the voltage of the zinc-ion battery system remained fixed after it was bent at totally different angles.

As well as, the electrochemical efficiency of the hydrogel electrolyte at 5 A·g-1 is 185 mAh·g-1. In Zn//Zn battery, the capability retention price of 10,000 cycles is 88 p.c, and the cycle stability of three,000 cycles is improved.

This technique supplies a brand new concept for the design of practical electrolyte of aqueous zinc-ion batteries.

Electric gains in battery performance

Extra info:
Tingting Wei et al, Bonding interplay regulation in hydrogel electrolyte allow dendrite-free aqueous zinc-ion batteries from −20 to 60 °C, Chemical Engineering Journal (2022). DOI: 10.1016/j.cej.2022.134646
Offered by
Chinese Academy of Sciences

Vast-temperature-window hydrogel electrolyte developed for aqueous zinc-ion battery (2022, February 18)
retrieved 20 February 2022

This doc is topic to copyright. Other than any truthful dealing for the aim of personal research or analysis, no
half could also be reproduced with out the written permission. The content material is offered for info functions solely.


Please enter your comment!
Please enter your name here